METHYL (TRIMETHYLSILYL)ACETATE
- Product Name
- METHYL (TRIMETHYLSILYL)ACETATE
- CAS No.
- 2916-76-9
- Chemical Name
- METHYL (TRIMETHYLSILYL)ACETATE
- Synonyms
- Methyl 2-(triMethylsilyl)acetate;METHYLTRIMETHYLSILICATE;METHYL (TRIMETHYLSILYL)ACETATE;Methyl (trimethylsilyl)acetate,98%;Trimethylsilylacetic acid methyl ester;2-(Trimethylsilyl)acetic acid methyl ester;Acetic acid, 2-(trimethylsilyl)-, methyl ester;2-[Dimethyl(methyl)silyl]acetic acid methyl ester
- CBNumber
- CB7704732
- Molecular Formula
- C6H14O2Si
- Formula Weight
- 146.26
- MOL File
- 2916-76-9.mol
METHYL (TRIMETHYLSILYL)ACETATE Property
- Boiling point:
- 38-39 °C13 mm Hg(lit.)
- Density
- 0.891 g/mL at 25 °C(lit.)
- refractive index
- n20/D 1.414(lit.)
- Flash point:
- 91 °F
- storage temp.
- Flammables area
- Specific Gravity
- 0.890
- Hydrolytic Sensitivity
- 2: reacts with aqueous acid
- BRN
- 1098961
Safety
- Hazard Codes
- F,Xi
- Risk Statements
- 11-36/37/38
- Safety Statements
- 16-26-36
- RIDADR
- UN 3272 3/PG 3
- WGK Germany
- 3
- F
- 10-21
- TSCA
- No
- HazardClass
- 3.1
- PackingGroup
- II
- HS Code
- 29319090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H226Flammable liquid and vapour
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 234966
- Product name
- Methyl trimethylsilylacetate
- Purity
- 97%
- Packaging
- 5g
- Price
- $79.6
- Updated
- 2023/01/07
- Product number
- M322525
- Product name
- Methyl2-(Trimethylsilyl)acetate
- Packaging
- 1g
- Price
- $45
- Updated
- 2021/12/16
- Product number
- JK283775
- Product name
- Methyl trimethylsilylacetate
- Purity
- 98%
- Packaging
- 5g
- Price
- $67
- Updated
- 2021/12/16
- Product number
- 8796AJ
- Product name
- Methyl trimethylsilylacetate
- Packaging
- 5g
- Price
- $117
- Updated
- 2021/12/16
- Product number
- JK283775
- Product name
- Methyl trimethylsilylacetate
- Purity
- 98%
- Packaging
- 25g
- Price
- $192
- Updated
- 2021/12/16
METHYL (TRIMETHYLSILYL)ACETATE Chemical Properties,Usage,Production
Chemical Properties
CLEAR COLOURLESS LIQUID
Uses
Methyl 2-(Trimethylsilyl)acetate is a useful compound in the organic synthesis.
General Description
Methyl trimethylsilylacetate on reaction with lithium diisopropylamide in THF at -78°C yields methyl lithiotrimethylsilylacetate. It also undergoes Peterson olefination to yield mainly Z-isomers of steroid 17β-side chain methyl acrylates.
Purification Methods
Methyl trimethylsilylacetate [2916-76-9] M 146.3, b 65-68o/50mm, d 4 0.89. Dissolve it in Et2O, shaken with 1M HCl, wash with H2O, aqueous saturated NaHCO3, H2O again, and dry it (a precipitate may be formed in the NaHCO3 solution and should be drawn off and discarded). The solvent is distilled off, and the residue is fractionated through a good column. IR (CHCl3) max 1728cm1 . [Fessenden & Fessenden J Org Chem 32 3535 1967, Matsuda et al. J Org Chem 45 237 1980, Beilstein 4 III 1855, 4 IV 3974 for Et ester.]
METHYL (TRIMETHYLSILYL)ACETATE Preparation Products And Raw materials
Raw materials
Preparation Products
METHYL (TRIMETHYLSILYL)ACETATE Suppliers
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- 1-516-6625404
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View Lastest Price from METHYL (TRIMETHYLSILYL)ACETATE manufacturers
- Product
- Methyl (trimethylsilyl)acetate 2916-76-9
- Price
- US $1.00/g
- Min. Order
- 1g
- Purity
- Min98% HPLC
- Supply Ability
- g/kg/ton
- Release date
- 2019-12-28